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Effect of the hydrogen flow rate on the structural and optical properties of hydrogenated amorphous silicon thin films prepared by plasma enhanced chemical vapor deposition

Identifieur interne : 000243 ( Main/Exploration ); précédent : 000242; suivant : 000244

Effect of the hydrogen flow rate on the structural and optical properties of hydrogenated amorphous silicon thin films prepared by plasma enhanced chemical vapor deposition

Auteurs : Sana Ben Amor [Tunisie] ; Wissem Dimassi [Tunisie] ; Mohamed Ali Tebai [Tunisie] ; Hatem Ezzaouia [Tunisie]

Source :

RBID : ISTEX:D716224DFA7F9A48547BC9F0BD3BD36706368750

English descriptors

Abstract

Hydrogenated amorphous silicon (a‐Si:H) thin films were deposited from pure silane (SiH4) and hydrogen (H2) gas mixture by plasma enhanced chemical vapor deposition (PECVD) method at low temperature (400 °C) using high rf power (60 W). The structural and optical properties of these films are systematically investigated as a function of the flow rate of hydrogen (F H 2).The surface morphology is analyzed by atomic force microscopy (AFM). The characterization of these films with low angle X‐ray diffraction revealed that the crystallite size in the films tends to decrease with increase in (F H 2). The Fourier transform infrared (FTIR) spectroscopic analysis showed that at low values of (F H 2), the hydrogen is predominantly incorporated in Si:H films in di‐hydrogen (Si‐H2) and (Si‐H2)n complexes. However, with increasing (F H 2) the hydrogen bonding in Si:H films shifts from di‐hydrogen (Si‐H2) and (Si‐H2)n complexes to the mono‐hydrogen (Si‐H) bonding configuration. Finally, for these optimized conditions, the deposition rate decreases with increasing F H 2 (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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DOI: 10.1002/pssc.201200238


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